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TABLE OF CONTENTS

Liquid Scintillation Spectrometry 1992
John E. Noakes, Franz Schönhofer, Henry A. Polach, Editors

Proceedings of the International Conference on
Advances in Liquid Scintillation Spectrometry
Vienna, Austria, September 14-18, 1992

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PREFACE ....................................................................................................................  v

ACKNOWLEDGMENTS ................................................................................................. vii

A TRIBUTE TO JOHN W. McKLVEEN ............................................................................ viii

EDITORS .................................................................................................................... xi

PARTICIPANTS .......................................................................................................... xiii


INTRODUCTION

The History of Liquid Scintillation Counting: A Personal View
C-T Peng ..................................................................................................................... 1


METHODS

Sample Preparation and Measurement Techniques

Assessment of New Features on a Commercial Liquid
Scintillation Spectrometer for Radiocarbon Dating
G T Cook and Robert Anderson ..................................................................................  17

A Combined LSC/NaI System for Low-Level
Environmental Measurements
Pall Theodorsson, S A Einarsson and E D Ơlafsdóttir ...................................................  23

Microvolume Liquid Scintillation Counting With Plate Counters
Tuula Stark and Tapio Yrjönen ...................................................................................  31

Single Photomultiplier Technology for Scintillation Counting in Microplates
Bernie Effertz, Ken Neumann and David Englert .........................................................  37

Optimization and Calibration of a Low Background Liquid Scintillation
Counter for the Simultaneous Determination of Alpha and Beta
Emitters in Aqueous Samples
J A Sanchez-Cabeza, Lluis Pujol, Joan Merino, Luis Leon, Jaume Molero,
Aleix Vidal-Quadras, W R Schell and P I Mitchell.............................................................
43

Selectable Delay Before Burst - A Novel Feature to
Enhance Low-Level Counting Performance
C J Passo, Jr. and M J Kessler ......................................................................................  51

Comparison of a Modified Integral Counting Method and Efficiency Tracing
Method for the Determination of Rn-222 by Liquid Scintillation Counting
Yoshio Homma, Yuko Murase and Keiko Handa............................................................ 59

Determination of Atmospheric Radioactivity Using a
Membrane Filter and Liquid Scintillation Spectrometry
Yoshio Homma, Yuko Murase and Keiko Handa ..........................................................  63

Reliability of Activity Determined by Cerenkov
Measurements in a Liquid Scintillation Counter
Makoto Takiue, Haruo Fujii and Tamaru Aburai ........................................................... 69

Low-Level Pu-241 Analysis by Supported-Disk Liquid Scintillation Counting
T P Ryan, P I Mitchell, J Vives i Batlle, J A Sanchez-Cabeza,
A T McGarry and W R Schell
......................................................................................  75

The Determination of Low Levels of Radium Isotopes and Radon
by Delayed-Coincidence Liquid Scintillation Spectrometry
Ferdinand Buheitel ..................................................................................................... 83

The Effect of Counting Conditions on Determining
Radiostrontium and Other Beta Emitters
by Liquid Scintillation
M M Ribera, J S Mestres, J F Garcia and Gemma Rauret ..............................................  89

Adsorption Correction in Ca-45 and Sr-89 Activity
Determination by Liquid Scintillation Counting
Leonor Rodríguez Barquero and J M Los Arcos ............................................................. 97

In-Line Control of a Waste Treatment Process by Solid Scintillation Counting
Ulrich Wenzel ..........................................................................................................  105

Production of Impurities in Benzene Synthesis for Liquid Scintillation
Counting and its Effect on
High-Precision Radiocarbon Measurements
David Witkin, R M Kalin, Austin Long, M J Rigali and Bartholomew Nagy .....................  115

Radiocarbon Dating Beyond 50,000 Years by Liquid Scintillation Counting
F G McCormac, R M Kalin and Austin Long ................................................................  125

Counting Performance and Design of 0.3-ml to 10-m1 Synthetic Silica
Liquid Scintillation
Vials for Low-Level C-14 Determination
A G Hogg ................................................................................................................. 135


Scintillators and Solvents

The Role of Auxiliary Scintillators for Gamma Spectroscopy and
Low-Level Counting Applications
John E Noakes, Robert J Valenta and Robert S Schreiner............................................ 143

Analysis of Solvent Components in Commercial Liquid Scintillation Cocktails
C-T Peng and S Q Liu ..............................................................................................  157

A Study of Several Commercial Liquid Scintillation Cocktails
for Measurement of Low Levels of Tritium in Water
J S Mestres, Pilar Rajadel and Gemma Rauret ............................................................ 165

A Meltable Thermoplastic Scintillator
Jari Suontausta, Timo Oikari and Stuart Webb ..........................................................  173

Plastic Scintillators: Some Novel Applications
James Thomson........................................................................................................ 179

Effect of Viscosity on Quench Characteristics of Solvents for
Liquid Scintillation Counting
Jan ter Wiel .............................................................................................................  185


Alpha Measurements

The Growth of a Radioanalytical Method: Alpha Liquid
Scintillation Spectrometry
W Jack McDowell and Betty L McDowell ....................................................................  193

Alpha Liquid Scintillation Analysis: Some Recent
Developments and Applications
Dazhu Yang .............................................................................................................  201

Determination of Uranium Series Radionuclide Pa-231
Using Liquid Scintillation Counting
Leena Saarinen and Juhani Suksi .............................................................................  209

Simultaneous Measurement of Alpha and Beta Emissions on Ready Cap®
Stephen W Wunderly ................................................................................................ 217

The Relation Between Photomultiplier Tube Output
Pulse Shapes and Alpha/Beta Separation Efficiency
J M Pates, G T Coop A B MacKenzie and James Thomson............................................. 225

Liquid Scintillation Counting of Plutonium and/or Americium Concentrations
Jozef L Parus, Wolfgang Raab and Tomasz Radoszewski .............................................  233


Standardization

Double-Label Counting of Heterogeneous Samples
Agustin Grau Carles, Leonor Rodríguez Barquero
and Agustin Grau Malonda
.......................................................................................  239

Throughput and Time Distribution Equations Revisited
Charles L Dodson....................................................................................................... 249

The ETDCR Method of Standardizing Fe-55 and Mn-54
Ryszard Broda and Krzysztof Pochwalski ....................................................................  255

CIEMAT/NIST Standardization Method Extended to Anode
Outputs for Beta and Electron-Capture Nuclides
J F Ortiz, J M Los Arcos and Agustin Grau Malonda .....................................................  261

Liquid Scintillation Standardization of Ba-133
Andrzej Chylinski and Tomasz Radoszewski ...............................................................  269



BIOSCIENCE APPLICATIONS

Liquid Scintillation Counting in Molecular Biology
C G Potter................................................................................................................. 277

Recent Advances in Scintillation Proximity Assay (SPA) Technology
R A Jessop ...............................................................................................................  285

Biological Applications of Microplate Scintillation Counting
Ken Neumann, David Englert and Norbert Roessler ...................................................  291

The Measurement of Cytotoxic T Lymphocyte Activity During Virus Infection
Frances Gotch .........................................................................................................  297

Scintillating Microtitration Plates in Immunoassays
Harri Siitari and Timo Oikari ......................................................................................  301

Simple Detection Method of P-32- and H-3-Labeled DNA Probes
Harri Siitari, Liisa Meriö and Antti Iitiä .......................................................................  307

"Filterscint": A High Efficiency Scintillation
Technique for H-3-Labeled Harvested Samples
C G Potter.................................................................................................................. 313

An Epidemiological Study Using Passive Radon
Measurement by Liquid Scintillation Counting
R J A Kappel, Gert Keller, Lothar Kreienbrock and R M Nickels .....................................  319


ENVIRONMENTAL APPLICATIONS

Tritium

Environmental Tritium in Hydrology: Present State (1992)
Dieter Rank............................................................................................................... 327

Continuous Tritium Effluent Water Monitor at the Savannah River Site
K J Hofstetter and H T Wilson ...................................................................................  335

A Regional Network for Investigating Atmospheric Tritium
György Uchrin, Kristóf Kozác, Eszter Csaba,
Dieter Rank and Vinzenz
Rajner................................................................................. 343

Determination of Environmental Tritium in Tree Rings
Gabriele Wallner ......................................................................................................  349

Electrolytic Tritium Enrichment of Natural Water Samples for Tritium Analysis
Uwe Morgenstern, Detlef Hebert and Werner Stolz ....................................................  355


Radon and Radium

Measurement of Low Levels of Rn-222 in Water With
Different Commercial Liquid Scintillation Counters
and Pulse-Shape Analysis
Laina Salonen ..........................................................................................................  361

Determination of Rn-222 in Drinking Water Using
an Alpha/Beta Liquid Scintillation Counter
J D Spaulding and J E Noakes ...................................................................................  373

Liquid Scintillation Counting Measurements of Radon from
Seepage Groundwater in Lake Biwa, Japan
Kimiko Horiuchi, Tadashi Ishii and Masao Kobayashi ..................................................  383

Determination of Ra-226 in Lake Sediments by Liquid
Scintillation Counting of Cocktail-Extracted Rn-222
Karl Irlweck and Gabriele Wallner ..............................................................................  391

Determination of Ra-226, Ra-228 and Ra-224 in
Water and Aqueous Solutions by Means of
Liquid Scintillation Counting
Stanislaw Chalupnik and J M Lebecka ........................................................................  397

Measurements of Ra-226, Rn-222 and Uranium in
Ukrainian Groundwater Using Ultra-Low-Level
Liquid Scintillation Counting
A V Zelensky, M G Buzinny, I P Los' ..........................................................................  405

Rapid Determination of Ra, Rn, Pb, and Po in Water
Using Extractive Liquid Scintillation
Siegurd Möbius, Poonsak Kamolchote, Tiana-Lalao
Ramamonjisoa and Mingde Yang
..............................................................................  413


Other Environmental Applications

The Determination of Th-234 in Oceanic Tracer Studies by Liquid Scintillation
Spectrometry Employing Alpha/Beta Separation Techniques
J M Pates, Robert Anderson, G T Cook and A B MacKenzie ..........................................  417

Measurement of Isotopic Uranium in Texas Drinking Water
Supplies by Liquid Scintillation With Alpha-Beta Discrimination
E A Venso, H M Prichard and C L Dodson ...................................................................  425

Control of Wastewater from a Nuclear Research Institute for
Compliance by Liquid Scintillation Spectrometry
Franz Schönhofer and Karl Buchtela ..........................................................................  431

A Rapid Method for Determining Sr and Sr-90 from Nuclear Accidents
Kurt Vogl and Paul Gesewsky...................................................................................... 435

Beta-Spectrometric Determination of Sr-90 in Water, Milk and
Other Samples With an Ultra-Low-Level Liquid Scintillation Counter
M G Buzinny, A V Zelensky and I P Los'....................................................................... 439

Environmental Monitoring of C-14 in Milk and Agricultural Samples
James B Moore, John E Noakes and James D Spaulding ..............................................  447

Liquid Scintillation Counting of Pb-210 in Grass and Soil
J M Lebecka, Antoni Mielnikow, Stanislaw Chalupnik and Krystan Skubacz.................... 455

Simultaneous LSC Measurement of K3Co-60(CN)6 and
114mInEDTA Tracers in Groundwater
J M Lebecka, Wojciech Soltyk and Jolanta Walendziak .................................................  461

Current Status of Liquid Scintillation at Westinghouse Hanford Company
J M Barnett, R A Jones, G S Barney, J E Kurtz, E M Colbert,
S A Callow and D C Hetzer
........................................................................................  467

AUTHOR INDEX ........................................................................................................  473

SUBJECT INDEX .......................................................................................................  477